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Organic and Inorganic Markers and Stable C-, N-isotopic Compositions of Tropical Coastal Aerosols from Megacity Mumbai: Sources of Organic Aerosols and Atmospheric Processing : Volume 12, Issue 8 (17/08/2012)

By Aggarwal, S. G.

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Book Id: WPLBN0003981613
Format Type: PDF Article :
File Size: Pages 38
Reproduction Date: 2015

Title: Organic and Inorganic Markers and Stable C-, N-isotopic Compositions of Tropical Coastal Aerosols from Megacity Mumbai: Sources of Organic Aerosols and Atmospheric Processing : Volume 12, Issue 8 (17/08/2012)  
Author: Aggarwal, S. G.
Volume: Vol. 12, Issue 8
Language: English
Subject: Science, Atmospheric, Chemistry
Collections: Periodicals: Journal and Magazine Collection (Contemporary), Copernicus GmbH
Publication Date:
Publisher: Copernicus Gmbh, Göttingen, Germany
Member Page: Copernicus Publications


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Kawamura, K., Umarji, G. S., Tachibana, E., Gupta, P. K., Patil, R. S., & Aggarwal, S. G. (2012). Organic and Inorganic Markers and Stable C-, N-isotopic Compositions of Tropical Coastal Aerosols from Megacity Mumbai: Sources of Organic Aerosols and Atmospheric Processing : Volume 12, Issue 8 (17/08/2012). Retrieved from

Description: National Physical Laboratory, Council of Scientific and Industrial Research, New Delhi 110012, India. To better understand the sources of PM10 samples from Mumbai, India, aerosol chemical compositions, i.e. total carbon (TC), organic carbon (OC), elemental carbon (EC), water-soluble organic carbon (WSOC), and inorganic ions were studied together with specific markers such as methanesulfonate (MSA), oxalic acid (C2), azelaic acid (C9), and levoglucosan. The results revealed that biofuel/biomass burning and fossil fuel combustion are the major sources of the Mumbai aerosols. Nitrogen-isotopic (Δ15N) composition of aerosol total nitrogen, which ranged from 18.1 to 25.4‰, also suggest that biofuel/biomass burning is the dominant source in both summer and winter seasons. Aerosol mass concentrations of major species increased 3–4 times in winter compared to summer, indicating an enhanced emission from these sources in winter season. Photochemical production tracers, C2 diacid and nssSO42− do not show diurnal changes. Concentrations of C2 diacid and WSOC show a strong correlation (r2 = 0.95). In addition, WSOC to OC (or TC) ratios remain almost constant for day- (0.37 ± 0.06 (0.28 ± 0.04)) and nighttime (0.38 ± 0.07 (0.28 ± 0.06)), suggesting that mixing of fresh secondary organic aerosols is not significant rather the Mumbai aerosols are photochemically well processed. Concentrations of MSA and C9 diacid present a positive correlation (r2 = 0.75), indicating a marine influence on Mumbai aerosols in addition to local/regional influence. Backward air mass trajectory analyses further suggested that the Mumbai aerosols are largely influenced by long-range continental and regional transport. Stable C-isotopic ratios (Δ13C) of TC ranged from −27.0 to −25.4‰ with slightly lower average (−26.5 ± 0.3‰) in summer than in winter (−25.9 ± 0.3‰). Positive correlation between WSOC/TC ratios and Δ13C values suggested that the increment in Δ13C of wintertime TC may be caused by prolonged photochemical processing of organic aerosols in this season. This study suggests that in winter, the tropical aerosols are more aged due to longer residence time in the atmosphere than in the summer aerosols.

Organic and inorganic markers and stable C-, N-isotopic compositions of tropical coastal aerosols from megacity Mumbai: sources of organic aerosols and atmospheric processing

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